Type

Text

Type

Thesis

Advisor

Sampath, Sanjay | Herbert Herman | Albert Tobin.

Date

2010-12-01

Keywords

Composites, Free-Standing Deposits, Heat Treatment, Mechanical Properties, Phase Transformations, Thermal Spray | Materials Science

Department

Department of Materials Science and Engineering

Language

en_US

Source

This work is sponsored by the Stony Brook University Graduate School in compliance with the requirements for completion of degree.

Identifier

http://hdl.handle.net/11401/72571

Publisher

The Graduate School, Stony Brook University: Stony Brook, NY.

Format

application/pdf

Abstract

The microstructure and properties of plasma-sprayed ceramics and ceramic matrix composites (CMCs) have been investigated. Substrate-free deposits were fabricated by plasma spraying onto expendable graphite substrates. The deposits were evaluated in the as-sprayed and heat-treated conditions. X-ray diffractometry (XRD) was used in conjunction with differential scanning calorimetry (DSC) to examine the phase content and transformation temperatures of plasma-sprayed Al2O3. Mechanical properties were measured using three-point flexural testing and density measurements were made for both the as-sprayed and heat treated conditions. Significant increases in modulus and strength were achieved as a result of post. spray heat treatment.Having established baseline properties with respect to the pure matrix material, the effect of incorporating a second phase was examined. Ceramic matrix composites were fabricated by plasma-spraying a mechanical mixture of Al2O3 and SiC particulate. Composites consisted of particulate SiC and re-solidified inclusions in an Al2O3 matrix. Significant improvements in strength and modulus resulted from the incorporation of second phase combined with heat-treatment

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